| Final 21:45 | Team | Time | L | | 1. Anastasiya Kapachinskaya |  RUS | 22.38s | 5 | | 2. Torri Edwards |  USA | 22.47s | 2 | | 3. Muriel Hurtis |  FRA | 22.59s | 4 | | 4. Zhanna Block |  UKR | 22.92s | 3 | | 5. Beverly McDonald |  JAM | 22.95s | 8 | | 6. Natalya Safronnikova |  BLR | 22.98s | 1 | | 7. Anzhela Kravchenko | UKR | 23.00s | 7 | | DQ Kelli White | USA | 22.05s | 6 |
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| Heat 1 19.40h | Time | Team | L | | 1. Zhanna Block | UKR | 22.61s | 6 | | 2. Anzhela Kravchenko | UKR | 22.66s | 4 | | 3. Beverly McDonald | JAM | 22.92s | 7 | | 4. Mary Onyali-Omagbemi |  NGR | 22.97s | 5 | | 5. Lauren Hewitt |  AUS | 23.07s | 8 | | 6. Roxana Diaz |  CUB | 23.12s | 1 | | 7. Vida Anim |  GHA | 23.16s | 2 | | -. Kelli White | USA | DQ | 3 |
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| Heat 2 19.48h | Time | Team | L | | 1. Muriel Hurtis | FRA | 22.41s | 6 | | 2. Anastasiya Kapachinskaya | RUS | 22.43s | 5 | | 3. Torri Edwards | USA | 22.44s | 3 | | 4. Natalya Safronnikova | BLR | 22.76s | 4 | | 5. Kim Gevaert |  BEL | 22.86s | 7 | | 6. Maryna Maydanova | UKR | 22.91s | 2 | | 7. Cydonie Mothersill |  CAY | 23.07s | 1 | | 8. Mercy Nku | NGR | 23.62s | 8 |
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| Heat 1 20.00h | Time | Team | L | | 1. Torri Edwards | USA | 22.66s | 6 | | 2. Anzhela Kravchenko | UKR | 22.81s | 4 | | 3. Vida Anim | GHA | 22.95s | 3 | | 4. Beverly McDonald | JAM | 22.96s | 5 | | 5. Merlene Ottey |  SLO | 23.22s | 1 | | 6. Johanna Manninen |  FIN | 23.42s | 2 | | 7. Anna Pacholak |  POL | 23.43s | 7 | | -. Digna Luz Murillo |  COL | DNS | 8 |
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| Heat 2 20.06h | Time | Team | L | | 1. Anastasiya Kapachinskaya | RUS | 22.73s | 5 | | 2. Kim Gevaert | BEL | 22.91s | 4 | | 3. Maryna Maydanova | UKR | 22.93s | 3 | | 4. Debbie Ferguson |  BAH | 22.98s | 8 | | 5. Abiodun Oyepitan |  GBR | 23.42s | 2 | | 6. Jacqueline Poelman |  NED | 23.51s | 7 | | -. Kelli White | USA | DQ | 6 | | -. Sharon Cripps | AUS | DNS | 1 |
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| Heat 3 20.12h | Time | Team | L | | 1. Muriel Hurtis | FRA | 22.70s | 4 | | 2. Natalya Safronnikova | BLR | 22.96s | 7 | | 3. Mercy Nku | NGR | 23.16s | 5 | | 4. Cydonie Mothersill | CAY | 23.29s | 3 | | 5. Svetlana Goncharenko | RUS | 23.29s | 2 | | 6. Allyson Felix | USA | 23.33s | 8 | | 7. Fabienne Feraez |  BEN | 24.17s | 1 | | -. Aleen Bailey | JAM | DNF | 6 |
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| Heat 4 20.18h | Time | Team | L | | 1. Zhanna Block | UKR | 22.67s | 6 | | 2. Mary Onyali-Omagbemi | NGR | 22.73s | 5 | | 3. Lauren Hewitt | AUS | 23.10s | 4 | | 4. Roxana Diaz | CUB | 23.21s | 8 | | 5. Sylviane Felix | FRA | 23.27s | 3 | | 6. Karin Mayr-Krifka |  AUT | 23.30s | 2 | | 7. Geraldine Pillay |  RSA | 23.39s | 1 | | 8. Joice Maduaka | GBR | 23.51s | 7 |
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| Heat 1 10.45h | Time | Team | L | | 1. Zhanna Block | UKR | 23.13s | 6 | | 2. Sylviane Felix | FRA | 23.29s | 4 | | 3. Johanna Manninen | FIN | 23.43s | 2 | | 4. Allyson Felix | USA | 23.46s | 7 | | 5. Roxana Diaz | CUB | 23.47s | 8 | | 6. Virgil Hodge |  SKN | 24.17s | 3 | | 7. Yana Kolpakova |  AZE | 27.74s | 5 |
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| Heat 2 10.51h | Time | Team | L | | 1. Muriel Hurtis | FRA | 22.51s | 7 | | 2. Vida Anim | GHA | 23.08s | 8 | | 3. Svetlana Goncharenko | RUS | 23.18s | 5 | | 4. Debbie Ferguson | BAH | 23.18s | 2 | | 5. Sharon Cripps | AUS | 23.29s | 6 | | 6. Digna Luz Murillo | COL | 23.48s | 4 | | 7. Huong Vu Thi |  VIE | 24.63s | 3 |
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| Heat 3 10.57h | Time | Team | L | | 1. Maryna Maydanova | UKR | 23.03s | 5 | | 2. Beverly McDonald | JAM | 23.11s | 2 | | 3. Karin Mayr-Krifka | AUT | 23.25s | 8 | | 4. Abiodun Oyepitan | GBR | 23.30s | 6 | | 5. Valma Bass |  ISV | 24.16s | 3 | | 6. Mae Koime |  PNG | 26.03s | 4 | | -. Kelli White | USA | DQ | 7 |
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| Heat 4 11.03h | Time | Team | L | | 1. Anzhela Kravchenko | UKR | 22.78s | 7 | | 2. Torri Edwards | USA | 22.83s | 3 | | 3. Kim Gevaert | BEL | 22.92s | 6 | | 4. Joice Maduaka | GBR | 23.11s | 8 | | 5. Natalya Safronnikova | BLR | 23.20s | 4 | | 6. Fabienne Feraez | BEN | 23.85s | 2 | | 7. Karla Hernandez |  ESA | 25.97s | 5 |
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| Heat 5 11.09h | Time | Team | L | | 1. Anastasiya Kapachinskaya | RUS | 22.90s | 6 | | 2. Aleen Bailey | JAM | 22.98s | 8 | | 3. Mercy Nku | NGR | 23.17s | 3 | | 4. Anna Pacholak | POL | 23.39s | 7 | | 5. Geraldine Pillay | RSA | 23.47s | 4 | | 6. Lineo Shoai |  LES | 25.63s | 5 | | -. Susanthika Jayasinghe |  SRI | DNS | 2 |
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| Heat 6 11.15h | Time | Team | L | | 1. Mary Onyali-Omagbemi | NGR | 22.80s | 8 | | 2. Cydonie Mothersill | CAY | 22.84s | 4 | | 3. Lauren Hewitt | AUS | 23.01s | 5 | | 4. Jacqueline Poelman | NED | 23.22s | 6 | | 5. Merlene Ottey | SLO | 23.24s | 7 | | 6. Lucia Ivanova |  SVK | 24.12s | 2 | | 7. Kerina Hughes |  AIA | 27.16s | 3 |
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