| Final | Team | time | Rk. | | 1. Gary Hall, Jr. |  USA | 21.93s | 1. 5. | | 2. Duje Draganja |  CRO | 21.94s | 5. 8. | | 3. Roland Schoeman |  RSA | 22.02s | 8. 1. | | 4. Stefan Nystrand |  SWE | 22.08s | 10.5. | | 5. Jason Lezak | USA | 22.11s | 7. 3. | | 6. Brett Hawke |  AUS | 22.18s | 10.2. | | 7. Oleksandr Volynets |  UKR | 22.26s | 8. 5. | | 8. Salim Iles |  ALG | 22.37s | 3. 4. |
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| Semi 1 | Team | time | Rk. | | 1. Roland Schoeman | RSA | 21.99s | 1. | | 2. Brett Hawke | AUS | 22.07s | 2. | | 3. Salim Iles | ALG | 22.16s | 4. | | 4. Julien Sicot |  FRA | 22.26s | 10. | | 5. Frédérick Bousquet | FRA | 22.29s | 12. | | 6. Javier Noriega |  ESP | 22.36s | 13. | | 7. Lyndon Ferns | RSA | 22.46s | 14. | | 8. Ricardo Busquets |  PUR | 22.52s | 15. |
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| Semi 2 | Team | time | Rk. | | 1. Jason Lezak | USA | 22.12s | 3. | | 2. Oleksandr Volynets | UKR | 22.18s | 5. | | 2. Gary Hall, Jr. | USA | 22.18s | 5. | | 2. Stefan Nystrand | SWE | 22.18s | 5. | | 5. Duje Draganja | CRO | 22.19s | 8. | | 6. Bartosz Kizierowski |  POL | 22.22s | 9. | | 7. Fernando Scherer |  BRA | 22.27s | 11. | | 8. Karel Novy |  SUI | 22.63s | 16. |
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| Heat 11 | Team | time | Rk. | | 1. Gary Hall, Jr. | USA | 22.04s | 1. | | 2. Salim Iles | ALG | 22.26s | 3. | | 3. Oleksandr Volynets | UKR | 22.41s | 8. | | 3. Roland Schoeman | RSA | 22.41s | 8. | | 5. Stefan Nystrand | SWE | 22.42s | 10. | | 6. Lyndon Ferns | RSA | 22.53s | 16. | | 7. Pieter van den Hoogenband |  NED | 22.56s | 17. | | 8. Ashley Callus | AUS | 22.82s | 26. |
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| Heat 10 | Team | time | Rk. | | 1. Frédérick Bousquet | FRA | 22.24s | 2. | | 2. Fernando Scherer | BRA | 22.52s | 14. | | 3. Johan Kenkhuis | NED | 22.58s | 18. | | 3. Aleksandr Popov |  RUS | 22.58s | 18. | | 5. Lorenzo Vismara |  ITA | 22.70s | 22. | | 6. Eduardo Lorente | ESP | 22.71s | 23. | | 7. Shyrshov Viacheslav | UKR | 22.96s | 28. | | 8. Matt Rose |  CAN | 23.01s | 30. |
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| Heat 9 | Team | time | Rk. | | 1. Bartosz Kizierowski | POL | 22.26s | 3. | | 2. Julien Sicot | FRA | 22.30s | 6. | | 3. Jason Lezak | USA | 22.33s | 7. | | 4. Brett Hawke | AUS | 22.42s | 10. | | 5. Javier Noriega | ESP | 22.52s | 14. | | 6. Michele Scarica | ITA | 22.80s | 25. | | 7. José Martín Meolans |  ARG | 22.90s | 27. | | 8. Andrey Kapralov | RUS | 22.97s | 29. |
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| Heat 8 | Team | time | Rk. | | 1. Duje Draganja | CRO | 22.28s | 5. | | 2. Ricardo Busquets | PUR | 22.45s | 12. | | 3. Karel Novy | SUI | 22.51s | 13. | | 4. Rafed Ziad El-Masri |  SYR | 22.58s | 18. | | 5. Marcos Hernández |  CUB | 23.19s | 34. |
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| Heat 7 | Team | time | Rk. | | 1. Rolandas Gimbutis |  LTU | 22.59s | 21. | | 2. Apostolos Tsangarakis |  GRE | 22.72s | 24. | | 3. Milorad Čavić |  YUG | 23.05s | 31. | | 4. Lee Chung-Hui |  KOR | 23.20s | 35. | | 5. Pedro Silva |  POR | 23.23s | 36. | | 5. Camilo Becerra |  COL | 23.23s | 36. | | 7. Jere Hård |  FIN | 23.33s | 41. | | 8. Chen Zuo |  CHN | 23.41s | 42. |
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| Heat 6 | Team | time | Rk. | | 1. Krisztián Takács |  HUN | 23.12s | 32. | | 2. Stanislav Neverovsky |  BLR | 23.13s | 33. | | 3. Kaan Tayla |  TUR | 23.26s | 39. | | 4. Julio Santos |  ECU | 23.43s | 43. | | 5. Khrysanthos Papakhrysanthou |  CYP | 23.51s | 45. | | 6. Arwut Chinnapasaen |  THA | 23.52s | 46. | | 7. Wang Shao-An |  TPE | 23.54s | 48. | | 8. Danil Haustov |  EST | 23.56s | 49. |
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| Heat 5 | Team | time | Rk. | | 1. Ravil Nachayev |  UZB | 23.23s | 36. | | 2. Carl Probert |  FIJ | 23.31s | 40. | | 3. Josh Laban |  USV | 23.43s | 43. | | 4. Hou Ming Ong |  MAS | 23.52s | 46. | | 5. Raychin Antonov |  BUL | 23.67s | 52. | | 6. Arnarson Örn |  ISL | 23.84s | 54. | | 7. Oleg Shteynikov |  KAZ | 23.88s | 55. | | 8. Semyon Danilov |  KGZ | 26.61s | 66. |
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| Heat 4 | Team | time | Rk. | | 1. José Mafio |  URU | 23.58s | 50. | | 2. Jevon Atkinson |  JAM | 23.61s | 51. | | 3. Rodrigo Díaz |  GUA | 23.69s | 53. | | 4. Terrence Haynes |  BBS | 23.90s | 56. | | 5. Abed Rahman Kaaki |  LEB | 24.68s | 57. | | 6. Gregory Arkhurst |  IVC | 24.82s | 58. | | 6. Mauricio Prudencio |  BOL | 24.82s | 59. | | 8. Alois Dansou |  BEN | 24.86s | 60. |
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| Heat 3 | Team | time | Rk. | | 1. Chris Hackel |  MRI | 25.33s | 62. | | 2. Cole Shade Sule |  CMR | 26.16s | 64. | | 3. Johnathan Steele | GRE | 26.40s | 65. | | 4. Kreshnik Gjata |  ALB | 26.61s | 66. | | 5. Hem Kiry |  CAM | 27.49s | 70. | | 6. Khaled Ghezzawi |  LIB | 27.55s | 71. | | 7. Hassan Mubah |  MLD | 27.71s | 73. | | 8. Edgar Luberenga |  UGA | 27.77s | 75. |
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| Heat 2 | Team | time | Rk. | | 1. Anderson Bonabart |  MKR | 26.75s | 68. | | 2. Hojamamed Hojamamedov |  TKM | 27.68s | 72. | | 3. Bounthanom Vongphachanh |  LAO | 28.17s | 77. | | 4. Leonce Sekama |  RWA | 28.99s | 78. | | 5. Mohamed Saad |  YEM | 29.97s | 80. | | 6. Mamadou Ouedraogo |  BFO | 30.36s | 81. | | 7. MLIque Williams |  ANT | 32.86s | 82. | | 8. Yona Walesi |  MWI | 34.11s | 83. |
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| Heat 1. | Team | time | Rk. | | 1. Rony Bakale |  CGO | 25.07s | 61. | | 2. Ahmed Mohamed Jewel |  BAN | 25.47s | 63. | | 3. Ibrahim Maliki |  NIG | 26.81s | 69. | | 4. Donnie Defreitas |  SVG | 27.72s | 74. | | 5. Abdourahamane Diawara |  GUI | 28.10s | 76. | | 6. David Keita |  MLI | 29.96s | 79. |
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